Sandstones are a major rock type in the 2500 m thick Palaeogene sedimentary fill of the Padesh strike-slip basin. The main diagenetic alterations include mechanical compaction and carbonate cementation while dissolution, transformation, recrystallization, replacement and chemical compaction were of lesser significance during burial. These postdepositional processes and their products are discussed in terms of micropetrographic characteristics, spatial distributional patterns, mechanisms of formation, controlling factors, and temporal sequence. The diagenetic changes are related to eodiagenesis, mesodiagenesis, and telodiagenesis but most processes occurred during the mesodiagenetic stage. The sandstone diagenesis was controlled by the depositional facies, climate conditions, primary mineralogy and fabric, distribution and composition of the associated shales, chemistry of the pore fluids, sedimentation and subsidence rates, burial depth, and basin thermal regime. The most peculiar feature is recorded in basal sandstone strata of the Palaeogene succession which display evidence for minor selective dissolution and subsequent kaolinite precipitation in the produced secondary pores as a result of thermal maturation of organic matter in the adjacent black shales. Several lines of evidence indicate a hyperthermal character of the Padesh Basin thus resembling other “hot-type” sedimentary basins.
The present study contributes to deciphering the diagenetic pathway of siliciclastic deposits in strike-slip basins characterized by elevated heat flow and can be applied for the evaluation of their hydrocarbon system potential. It also supports previous findings that thermal maturation of kerogene in carbonate-free, organic-rich shales may influence the mesodiagenetic alteration of adjacent sandstones in response to increased temperature.
The area of the town of Etropole is famous for the well-preserved Lower Bajocian ammonites, which can be still often found in the nearly located exposures. These ammonites were the source of a number of species that enabled the recognition of the Bajocian in Bulgaria. The ammonite faunas and their host rocks were allocated to a series of stratigraphic horizons that composed the stratotype section designated as the reference standard for the definition and characterization of the Etropole Formation. The latter includes an ammonite spectrum which is composed of both Lower Bajocian species of Northwest European distribution and proper Bulgarian dispersal. It contains rare examples of the ammonite families Graphoceratidae and Sphaeroceratidae, frequent ammonites of the family Sonniniidae, and much more common members of the families Oppeliidae, Otoitidae and Stephanoceratidae that define a biostratigraphic interval from the Hyperlioceras discites to the Stephanoceras humphriesianum zones. This paper deals with the Lower Bajocian ammonite specimens hosted in the collection of the Historical Museum in Etropole (Bulgaria). The best preserved and the most valuable examples of this collection are described and figured. Although not purposefully collected, these ammonites give an excellent impression of the relative abundances of what is common and typical for stratotype section of the Etropole Formation. The study of this collection has triggered the rocks of the Etropole Formation (including the type-section) to be biostratigraphically reassessed, but this will be done elsewhere. Considering that both exposures and the fossil-bearing levels previously known from the Etropole area have now nearly disappeared, the ammonite collection of the Historical Museum in Etropole provides authentic specimens to be viewed. Besides, the collection forms an integral part of the overall heritage of the Etropole region and therefore offers both scientific and educational values.
The local formation of quartz strain fringes around authigenic pyrite crystals and chamosite strain fringes around detrital grains is described from Hirnantian glaciomarine diamictites (Sirman Formation) of the Palaeozoic Balkan Terrane, now cropping out in the Alpine western Srednogorie Zone. The fringes belong to the antitaxial type and are interpreted as products of synkinematic, low temperature growth in microdilatation sites as a result of diffusive mass-transfer processes. The relatively simple fringe geometry and fiber orientation reflect coaxial progressive deformation that can be broadly related to the Variscan orogeny. Performed XRD analysis of shales intercalated with the diamictites indicates that the Upper Ordovician glacial deposits underwent a high-grade diagenetic alteration. Therefore, this study reports a rare case of development of strain fringes in non-metamorphosed sedimentary rocks.
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The Dvuyakornaya Formation in eastern Crimea of late Kimmeridgian to Berriasian age represents a thick flysch-like succession of clays, marls and less common limestones. The ammonite zonation includes incomplete record from the Beckeri Zone in the uppermost Kimmeridgian up to the Jacobi Zone in the Lower Berriasian. Two main sections have been micropalaeontologically studied – the Dvuyakornaya Buhta and the Cape Svyatogo Ili’i. Eighteen calpionellid species of the genera Longicollaria, Chitinoidella, Daciella, Dobeniella, Popiella, Praetintinnopsella, Tintinnopsella, Crassicollaria and Calpionella have been found. The calpionellid zones Chitinoidella (with Dobeni and Boneti subzones), Crassicollaria and Calpionella (with Alpina and Elliptica subzones) are described and directly correlated to the existing ammonite biostratigraphy. The Dobeni Subzone corresponds to a part of the barren interval between the ammonite Hybonotum and Microcanthum zones, the Boneti Subzone – to the Microcanthum Zone, and the Crassicollaria Zone – to the Durangites Zone p.p. and Jacobi Subzone p.p. The boundary between the Crassicollaria and Calpionella zones is within the Jacobi Subzone. In the Berriasian, the Alpina Subzone has been correlated to the Jacobi and Grandis subzones, and the Elliptica Subzone – to upper part of the Grandis Subzone that was characterized in the Dvuyakornaya Formation by diverse ammonite faunas of the “Feodosiya Marlstones”. Chitinoidellids of the Dobeni Subzone for the first time determine late Early Tithonian age in the area. Calpionellid to ammonite correlation of the Dvuyakornaya Formation is discussed in the light of previous direct correlations between macro- and microfossil biostratigraphy of the Tithonian and the Lower Berriasian in the Tethyan Realm.
Sedimentological and mineralogical composition of Upper Cretaceous terrigenous and volcaniclastic sandstones are presented for the Coşuştea Nappe of the South Carpathians, Romania, in order to constrain the provenance and tectonic setting of deposition. Existing geochemical data on volcaniclastic rocks were interpreted using discrimination diagrams in order to get additional information. The Coşuştea Nappe includes terrigenous turbidites, overlain by upward coarsening sequences of volcaniclastic turbidites, both associated with a strongly dismembered mélange complex. Facies association and vertical facies distribution suggest that terrigenous successions are midfan turbidites, dominated by deposition in suprafan channels. Their sandstone mineralogy indicates that a major sediment source, located on the upper plate, provided detritus of Getic type metamorphic basement and withinplate volcanic rocks, with minor input from the accretionary wedge. Volcaniclastic sedimentation took place as dominantly sandstone deposition in supracone lobes, followed by coarse sedimentation as channelized debris flows. Vertical facies distribution suggests evolution in time from midfan to proximal fan turbidites. Mineralogical composition of volcaniclastic sandstones indicates provenance from a major volcanic source, with minor contributions from the accretionary wedge and from an upper continental plate supplying terrigenous siliciclastic detritus, and suggests that volcaniclastic turbidites accumulated in a trench or a slope forearc basin. Geochemical data indicate resedimented volcanic arc material, with intermediate to basic composition and calc-alkaline geochemistry. The volcanic source was very likely represented by the Maastrichtian volcanism related to the Banatitic Magmatic and Metallogenetic Belt from the western South Carpathians.
This study aims to evaluate the activity concentrations of 238U, 226Ra, 232Th, 228Th and 40K along the beaches of Maronia and Samothraki being adjacent to the local granitoids. These range from 14-75, 17.5-114.8, 23.7-71.9, 24.5-71.6 and 262-1319 Bq/kg, respectively. The (wt.%) of heavy magnetic (HM) (amphibole, epidote, clinopyroxene, chlorite, magnetite and ilmenite) fraction, the heavy non-magnetic (HNM) (zircon and titanite) fraction, and the total heavy fraction (TH), were correlated with the concentrations of the measured radionuclides in the bulk samples. The measured radionuclides in the beach sands were normalized to the respective values measured in the granitic rocks, which are their most probable parental rocks, so as to provide data upon their enrichment or depletion. The annual effective dose varies between 0.004 and 0.013 mSv y-1 for tourists and from 0.016 to 0.056 mSv y-1 for local people working on the beach.
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