
This study presents new geochemical data on heavy metals and As in sediments from the Topolnitsa River catchment - a region of both historical and present-day industrial, mining, and agricultural activities. Systematic sampling, analysis, and sediment quality assessment were carried out following the EU Water Framework Directive and SIMONA project methodologies suitable for the predictive survey methods of metal contamination processes in fluvial sediment systems.
The sampling of bottom and floodplain sediments, as well as a single suspended sediment sample was performed in three strategic locations along the Topolnitsa River. We explored spatial and temporal patterns in heavy metal (Cu, Pb, Zn, Cd, Hg, Ni, Cr) and As distribution in those sediments. The results showed consistently higher heavy metal loads in river bottom sediments compared with flood sediments for most elements at a given location. The top flood sediments, on the other hand, had systematically lower heavy metal contents compared with bottom flood sediments.
The first monitoring point at Staria Kemer had significantly lower heavy metal concentrations for most elements compared with the other two locations (Chavdar and Petrich). On the other hand, As, Hg, Ni, and Pb contents in top flood sediments decreased from Chavdar to Petrich monitorimg points, the latter being the last location studied down the river course. Consistently high Cu concentrations in all analyzed samples indicate an ongoing and/or cycling pollution, suggesting the need for mitigation measures, as well as continued sediment monitoring.
This study documents the formation of optically anomalous biaxial apatite resulting from partial fluid-mediated metasomatic alteration of pegmatitic apatite containing a britholite component. The optical anomaly was identified using a refractometer. SEM and EDX data constrain alteration conditions to interaction with acidic, oxidizing, highly saline, Si-bearing fluids at temperatures below 400–500 °C, accompanied by elevated fluorine activity. Pervasive partial metasomatic modification produced patchy compositional zoning and increased porosity within the apatite crystals. Microscale variations in F, OH, and Cl define compositional domains with differing proportions of fluorapatite, hydroxylapatite, and chlorapatite end members. These chemical differences result in variable light propagation velocities and refractive indices, giving rise to anomalous biaxial optical behavior. Single-crystal X-ray diffraction shows that all crystals retain the hexagonal apatite structure (P6₃/m). At the same time, fluid-induced apatite alteration generated non-uniform channel-site occupancies, accompanied by substitution of apatite by britholite along with the formation of vacancies in the calcium positions, and local structural distortions without symmetry lowering. The integration of optical, structural, and chemical data demonstrates that microscale compositional heterogeneity, produced by fluid–apatite interaction, is responsible for the observed optical anomaly.
The Palaeozoic metamorphic basement hosting the Upper Cretaceous Elatsite porphyry-copper deposit in the Etropole Mountain consists of a greenschist facies fine-grained silicate to carbonate-silicate sedimentary sequence further affected by contact metamorphic transformations in a tide aureole next to the Upper Carboniferous Vezhen pluton. Field and petrographic observations distinguish alternating phyllite, chlorite-sericite-biotite, chlorite-sericite, and chlorite-sericite-calcite schists with chlorite and biotite porphyroblasts, and local carbonate and sulfide saturation. Their trace-element patterns, including LREE enrichment (LaN/SmN = 2.6–4.4), negative Eu anomalies (Eu/Eu* = 0.6–1.0), and low Zr/Sc–Th/Sc ratios indicate a felsic continental provenance with limited sediment recycling and deposition in a continental island-arc setting. Elevated Sr (up to 794 ppm) reflects primary carbonate input, while localized Cr-Ni enrichment (up to ~900 ppm and 440 ppm, respectively) is linked to Fe-oxides and sulfides rather than to a mafic protolith. U-Pb detrital zircon geochronology reveals two major age clusters, Neoproterozoic zircon cores (600–580 Ma) and Carboniferous zircon metamorphic rims (340–330 Ma), together with minor presence of younger Late Ordovician–Early Devonian ages (414–411 Ma). The obtained age of a hydrothermal rutile of ~100 ± 36 Ma records the influence of the Cretaceous hydrothermal activity on these rocks. All these data point to a complex evolution of the studied metamorphic basement including: (1) post-late Neoproterozoic sedimentation which continued up to Early Devonian, (2) mid Carboniferous greenschists facies metamorphism and late Variscan contact metamorphic transformations, and (3) Cretaceous hydrothermal overprint related to the porphyry-copper hydrothermal alteration and mineralization. These features suggest that the metamorphic basement of the Elatsite porphyry-copper deposit acted as a structurally and chemically active constituent, providing pathways for movement and sources of components for the hydrothermal fluids during the Late Cretaceous magmatic-hydrothermal activity.
Seventeen Neogene avian localities are documented in Bulgaria, including 12 Miocene and 5 Pliocene sites, distributed across lowland and semi-mountainous regions of both Northern and Southern Bulgaria. The known avifauna comprises 24 taxa, including three new genera — Euroceros (ground hornbill), Balcanas (dabbling duck), and Eremarida (lark) — and 11 new species, highlighting the previously underestimated diversity of Neogene birds in Southeastern Europe.
In addition to its taxonomic significance, the Bulgarian Neogene avifauna provides important insights into paleornithogeographic patterns in the Eastern Paratethys region. The composition of these assemblages indicates faunal affinities with both Western Eurasian and, to a lesser extent, Asian provinces, supporting the role of the Balkan region as a biogeographic corridor during the Neogene.
In a broader context, Bulgarian fossil birds represent a small but non-negligible fraction of the global Neogene avifauna, accounting for approximately 1.0 % of known taxa. Their stratigraphic distribution and taxonomic composition, however, suggest that the region preserves key evidence for avian dispersal and diversification in Southeastern Europe. These findings emphasize the importance of the Balkan Peninsula as an underexplored area with significant potential for refining Neogene avian paleobiogeography.
Soft-sediment deformation structures (SSDS) in the Upper Cretaceous sequence of the Chelopech sub-basin (Central Bulgaria) provide a high-resolution record of the regional geodynamic evolution, from syn-rift to orogenic stages. Detailed analysis identifies a high-density distribution of synsedimentary slump folds, convolute bedding, diapiric structures, and peperites. The stratigraphic distribution of these features reveals three distinct evolutionary phases: (1) Lower Turonian basal units characterized by storm-induced reworking during initial subsidence; (2) Middle Turonian (Chelopech Formation) peperites and clastic diapirs triggered by coupled seismic activity and sub-aqueous magmatism during the late syn-rift phase; and (3) Santonian–Maastrichtian (Mirkovo and Chugovitsa Formations) large-scale gravitational slumps and mass-gravity flows. This terminal phase reflects a shift toward regional tectonic inversion and steepened basin margins during orogenic closure. These results demonstrate that SSDS serve as a critical diagnostic tool for reconstructing the rapid transitions in the Srednogorie Zone tectonic regime.
This study focuses on the Trebeshina-Dhëmbel-Nemërçkë (TDN) karst massif, one of Albania’s largest karst regions. The study integrates field investigations, geological and hydrogeological mapping and observations, groundwater balance calculations, and hydrochemical and stable-isotope evidence. The main contribution of this study is explaining the karst massif's functioning by identifying the recharge area, calculating renewable groundwater resources, and determining groundwater discharge. The value of the study also lies in identifying the dominant hydrochemical processes and the role of the Permian evaporite formation underlying the Mesozoic carbonate rock in the hydrogeochemistry of karst water in the TDN massif. A better understanding of the massif, especially the Këlcyra Gorge (canyon), where many important karst springs emerge, is valuable because the Vjosa River catchment basin was designated a National Park in 2024 and holds international significance. In this context, knowing the quantity and quality of karst waters draining into the Këlcyra Gorge is essential, as they affect the overall quality of the Vjosa River. The TDN massif is a transboundary karst massif shared with Greece (UNECE, 2007), but no coordinated investigations have been conducted by either country to date. The massif's total renewable karst water resources are nearly 12.0 m³/s, most of which drain into the Këlcyra Gorge, with the remainder flowing into Greece. The results provide the first comprehensive hydrogeological synthesis of the TDN karst massif and establish a scientific basis for future sustainable management of the Vjosa National Park in general, which is also a transboundary aquifer shared between Albania and Greece. The study finds that the TDN massif is a typical Mediterranean karst area characterized by large hypsometric differences, which favor the formation of significant karst flows that recharge large karst springs with highly variable regimes.
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